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福建三都澳近岸表层沉积物稀土元素组成与物源判别

Composition and provenance discrimination of rare earth elements in surface sediments of coastal Sandu’ao, Fujian Province

  • 摘要: 为揭示稀土元素含量和分布特征,及其沉积环境及物源信息,本研究采集三都澳53个表层沉积物样品进行粒度与稀土元素测试分析。结果表明:研究区稀土元素平均含量为203.56 mg/kg,整体呈现出轻稀土相对富集而重稀土平缓的特点,Eu中度负异常,无明显的Ce异常。通过分析沉积物粒度参数,并结合Q型聚类分析,发现研究区沉积物粒度组成以粉砂为主,分为3类沉积区,大部分区域沉积环境较为稳定,受沉积物粒度与水动力影响较大。运用标准化配分模式、特征参数、富集因子(EF)及判别函数(DF)等分析显示,研究区主要为陆源,其中一部分物质可能为长江细颗粒物质沿着浙闽沿岸流南下并由于潮汐和波浪的推动作用与该区域进行水体交换而带来,潮汐和波浪还会对周边基岩剥蚀而产生大量碎屑物质,还有一部分物质可能为霍童溪、交溪等入海河流、溪流、冲沟等在洪水期携带的洪积物在此沉积。

     

    Abstract: In order to elucidate the content and distribution characteristics of rare earth elements (REEs), as well as their sedimentary environment and source information, this study conducted a comprehensive analysis on particle size and REE tests using 53 surface sediment samples collected from Sandu’ao. Results revealed that the average REE content in the study area was 203.56 mg/kg, demonstrating an overall enrichment of the light REEs compared to heavy REEs. A moderate negative Eu anomaly was observed, while no apparent Ce anomaly was observed. Through the examination of sediment particle size parameters and Q-type cluster analysis, it was found that the sediment particle size composition of the study area was mainly silt, categorized into three types of sediment areas. The majority of these areas exhibited a relatively stable sedimentary environment, significantly influenced by sediment particle size and hydrodynamics. The analysis of standardized distribution curves, characteristic parameters, enrichment factor (EF), and discriminant function (DF) show that the study area is mainly land-based sources. Part of the substances may be traced back to the Yangtze River, with fine particulate matter being transported southward along the Zhejiang-Fujian coast due to the push of tides and waves, leading to water body exchange in the region. Tides and waves also abraded the surrounding bedrock, producing a substantial amount of clastic material. Additionally, a fraction of the materials may originate from rivers, streams, and gullies such as Huotong and Jiaoxi rivers, being deposited during the flood.

     

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